REARRANGEMENT OF CARBOCATIONS DERIVED FROM ALCOHOLS

Authors

  • Ulug‘bek Xayrullo o‘g‘li Pardayev
  • Dildora O‘tkirjon qizi Choriqulova
  • Xurshida Rajabboyovna Kosimova

Keywords:

carbocation, rearrangement, alcohol, major product, hydrogen chloride, hydride shift, alkyl shift, unimolecular elimination, unimolecular substitution.

Abstract

In the intricate realm of organic chemistry, the rearrangement of carbocations stands as a fascinating and pivotal phenomenon, offering profound insights into the dynamic nature of molecular structures. Among the myriad sources from which carbocations can be derived, alcohols emerge as a particularly intriguing starting point. This article delves into the captivating world of rearrangements involving carbocations originating from alcohols, exploring the underlying principles, mechanisms, and the consequential impact on reaction pathways.

References

Vogel, Pierre. Carbocation Chemistry. Amsterdam: Elsevier Science Publishers B.V., 1985.

Olah, George A. and Prakash, G.K. Surya. Carbocation Chemistry. New Jersey: John Wiley & Sons, Inc., 2004.

Vollhardt, K. Peter C. and Schore, Neil E. Organic Chemistry: Structure and Function. New York: Bleyer, Brennan, 2007.

Bishop, R. Ritter-type Reactions / R. Bishop, ed. by P. Knochel, G. A. Molander, S. Burke // Comprensive Organic Synthesis Second Edition, Elsevier: Oxford. – 2014. – V. 6. – P. 239-296.

Moulay, S. The most well-known rearrangements in organic chemistry at hand / S. Moulay // Chemistry Education: Research and Practice. – 2002. – V. 3. – Iss. 1. – P. 33. (Scopus, Web of Science)

http://en.Wikipedia.org/wiki/Carboca..._rearrangement

https://byjus.com/jee/rearrangement-reactions-of-alkyl-carbocation/#:~:text=Carbocation%20rearrangement%20occurs%20when%20the,groups%20and%20holds%20a%20sextet.

https://www.masterorganicchemistry.com/2012/08/15/rearrangement-reactions-1-hydride-shifts/

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Published

2024-01-15

How to Cite

Pardayev, U. X. o‘g‘li, Choriqulova, D. O. qizi, & Kosimova, X. R. (2024). REARRANGEMENT OF CARBOCATIONS DERIVED FROM ALCOHOLS. Innovative Development in Educational Activities, 3(1), 49–55. Retrieved from https://openidea.uz/index.php/idea/article/view/2021